期刊
JOURNAL OF MEMBRANE SCIENCE
卷 613, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.memsci.2020.118517
关键词
PEM fuel Cell; Anti-oxidation; Cerium; 18-Crown-6 ether; Nafion; Radical scavenger
资金
- Korea Institute of Energy Technology Evaluation and Planning (KETEP), Republic of Korea [20173010032100]
- National Foundation of Korea, Republic of Korea [NRF2018M3D1A1058624]
- Korea Evaluation Institute of Industrial Technology (KEIT) [20173010032100] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The coordination complex of 18-crown-6 ether/cerium ions (CRE/Ce) is embedded in Nafion ionomer between catalyst and membrane layers in fabrication of membrane electrode assembly (MEA). The anti-oxidation effects of CRE/Ce on ionomer and MEA are investigated not only by Fenton's test but also by FT-IR and XPS, ex-situ and in-situ fluoride ion (F-) emission rate, and cell performance measurements. While Ce3+ plays an excellent role in scavenging HO center dot radicals, CRE alleviates migration of cerium ions out of the ionomer during cell operation. Both ex-situ and in-situ degradation rate tests show that the systems containing CRE/Ce emits much lower amount of fluoride and sulfonate (SO3-) ions than those without CRE/Ce. The open-circuit voltage (OCV) test at low humidity (30%) show that the cell containing the CRE/Ce is still alive even after 300 h operation, while other cells without it are terminated before it.
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