期刊
BIORESOURCE TECHNOLOGY
卷 315, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2020.123801
关键词
Pyrolytic bio-crude oil; Nitrogen transformation; Amino acid model compound; NOX precursor; Catalytic denitrogenation; N-containing heterocyclic compounds
资金
- National Natural Science Foundation of China [51808278]
- Natural Science Foundation of Jiangxi Province, China [20192BAB213012]
- Science and Technology Planning Project of Changsha [kq1802010]
- Forestry Science and Technology Planning Project of Hunan Province [XLK201938]
- Science and Technology Planning Project of Hunan Province [2018RS3109]
Pyrolysis of protein-rich biomass, such as microalgae, macroalgae, sewage sludge, energy crops, and some lignocellulosic biomass, produces bio-oil with high nitrogen (N) content, sometimes as high as 10 wt% or even higher. Major nitrogenous compounds in bio-oil include amines/amides, N-containing heterocycles, and nitriles. Such bio-oil cannot be used as fuel directly since the high N content will induce massive emission of nitrogen oxides during combustion. The present review comprehensively summarized the effects of biomass compositions (i.e., elemental, biochemical, and mineral compositions) and pyrolysis parameters (i.e., temperature, heating rate, atmosphere, bio-oil collection/fractionation methods, and catalysts) on the contents of N and the N-containing chemical components in bio-oil. The migration and transformation mechanisms of N during the pyrolysis of biomass were then discussed in detail. Finally, the research gaps were identified, followed by the proposals for future investigations to achieve the denitrogenation of bio-oil.
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