4.5 Article

3D carbon framework-supported FeSe for high-performance potassium ion batteries

期刊

SUSTAINABLE ENERGY & FUELS
卷 4, 期 9, 页码 4807-4813

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0se00146e

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资金

  1. National Natural Science Foundation of China [21773188]
  2. Fundamental Research Funds for the Central Universities [XDJK2019AA002]
  3. Postgraduate tutor team building project [XYDS201911]
  4. Program for Experimental Technology Research of Southwest University [SYJ2019006]

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FeSe@C with a 3D porous interconnected carbon framework is used as the anode for potassium ion batteries (PIBs). FeSe@C has a relatively large specific surface area and a superior microporous and mesoporous structure, thus facilitating the storage and transportation of potassium ions. When tested in PIBs as an anode, FeSe@C shows good specific capacity of 298.5 mA h g(-1)after 200 cycles at 500 mA g(-1), thus indicating good cycle stability. In addition, a possible potassium storage mechanism is explored. Moreover, the diffusion coefficient of potassium ions (D-K) of FeSe@C is 1.67 x 10(-10)cm(2)s(-1)is calculated. Therefore, the FeSe@C composite is expected to become the next-generation anode material for PIBs.

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