期刊
INORGANICA CHIMICA ACTA
卷 468, 期 -, 页码 77-81出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2017.04.055
关键词
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资金
- National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1412455] Funding Source: National Science Foundation
In aqueous media the host cucurbit[7] uril (CB7) forms inclusion complexes of high thermodynamic stability with ferrocenyl-containing guests. These complexes are characterized by the inclusion of the ferrocenyl group inside the CB7 cavity, primarily driven by hydrophobic forces. This mini-review provides a summary of the properties of these inclusion complexes, with emphasis on their electrochemical properties and, particularly, on the CB7-induced shift in the half-wave potential for one-electron oxidation of the ferrocenyl residues. (C) 2017 Elsevier B.V. All rights reserved.
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