期刊
INORGANIC CHEMISTRY
卷 56, 期 14, 页码 7657-7667出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b00112
关键词
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资金
- National Natural Science Foundation of China (NSFC) [91534102, 21271058]
- Anhui Provincial Science and Technology Department [1501021013]
- Intelligent Manufacturing Institute of Hefei University of Technology [IMICZ2015104]
A facile hydrolysis-coupled redox (HCR) reaction followed by postheating reduction has been designed to prepare unique 3D Cu/Fe3O4 core-shell nanorod array anodes. Fe2+ ions from fresh FeSO4 solution have been hydrolyzed and oxidized to form an Fe(OH)(3) shell on the surface of Cu(OH)(2) nanorods; meanwhile the resulting acidic environment induces the reduction of Cu(OH)(2) to Cu2O, which realizes an unusual redox reaction between Fe2+ ions and Cu(OH)(2). The reaction procedure and thermodynamics possibility between Fe2+ ions and Cu(OH)(2) nanorod arrays are discussed from the aspect of electrode potentials. After postheating reduction in Ar/H-2, the obtained 3D architecture of Cu current collector serves as a stout support for the Fe3O4 shell to form nanorod array anodes without using any binders or conducting agents. The resulting highly stable core-shell structure facilitates rapid and high-throughput transport pathways for ions/electrons and allows better accommodation of volume change during the repeated lithiation/delithiation. Its application as anodes in combination with LiNi0.5Mn1.5O4 cathodes for full cells demonstrates superior rate capability, enhanced energy density, and long cycling life.
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