期刊
INORGANIC CHEMISTRY
卷 56, 期 9, 页码 5361-5370出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b00467
关键词
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资金
- National Science Foundation [DMR-1411086]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1411086] Funding Source: National Science Foundation
Extending pi-conjugation of the diimine ligand (NN ligarid) via benzannulatiou is a common way to tune the absorption and emission energies of cationic iridittrin(III) complexes. However, it can cause either a red- or blue-shift of the absorption and emission bands depending on the site of benzannulation. To understand the mechanism of changes in optical transitions upon benzannulation on the diimine ligand,a series of new cationic iridium(III) complexes [Ir(dppi)(2)(NN)]PF6 (1-6) (where dppi =1,2-diphenylpyreno[4,5-d]iftiidazole; NN = 2-(pyridin,2:,yl)quinoline (1); 2-(pyriidin-2yi)-[7,8Thenzoquinoline (2), 2,2'-bisquinoline- (3), 2-(quinolin-2-yl)[7;8]benzoquineline- (4), 2-(pyridiri-2-y1)[6,7]benzoquifteline (5); 2[6,7]benzoquinoline (6)) containing diirriine ligand with 'varied degrees of pi-conjugation via :benzanntilatioti at different sites of the 2-(pyridn-2-yl)quinoline ligand were synthesized: Experimental results and density functional theory (DFT) calculations revealed that benzannulation at, the 6,7-position of quinoline and/or the 5',6' -position of pyridine (3, 5, and 6) induced red-shifts in their absorption and emission bands With respect to:the parent complex-1; while benzannulation at:the 7,8,position of quinoline resulted in blue-Shifts (2 vs 1 and 4 Thislphenomerion was rationalized by the summery of the frontier molecular orbitals at the site of benzannulation, which stabilized or destabilized the lowest unoccupied molecularr orbital (LUMO),upOn interactions with, 1,3-butadiene, while the energy of the highest occupied molecular orbital (HOMO) remained nearly the same. This discovery would enable a rational design of :organic or organometallic compounds that have predetermined: absorption and emission energies.
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