期刊
INORGANIC CHEMISTRY
卷 56, 期 5, 页码 3036-3043出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b03174
关键词
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资金
- National Natural Science Foundation of China [21277022, 21371030, 21301026, 21471029]
We herein report the porous 4-fold interpenetrated mog (moganite) metal organic framework (MOF) [Cd-3(tipp)(bpdc)(2)].DMA. 9H(2)O (1.Cd; H(2)tipp = 5,10,15,20-tetrakis(4-(imidazol-1-yl)pheny1)porphyrin, H(2)bpdc = biphenyl-4,4'-dicarboxylic acid, DMA = N,N'-dimethylacetamide). The incorporation of Cd and carboxylate oxygen affords 1.Cd rich Lewis acid and basic sites. This MOF 1.Cd was then applied as an efficient heterogeneous catalyst for the important cyanosilylation of aldehydes and Knoevenagel condensation reactions. 1.Cd features excellent catalytic performance and recyclability for the cyanosilylation of various aldehydes with trimethylsilyl cyanide (TMSCN). Moreover, 1.Cd shows highly efficient catalysis and substrate selectivity for Knoevenagel condensation reactions of various aldehydes with malononitrile. The high catalytic activity and stability toward C-C bond formation make 1.Cd a promising heterogeneous catalyst.
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