期刊
INORGANIC CHEMISTRY
卷 56, 期 9, 页码 4885-4897出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b03100
关键词
-
资金
- German Academic Exchange Service (Deutscher Akademischer Austauschdienst - DAAD)
Two new amphiphilic platinum(B) complexes, [Pt(2-(4-fluorophenyl)-5-(4-dodecyloxyphenyl)pyridine) (acac)]-(Pt-1) and [Pt(2-(4-dodecyloxyphenyl)-5-(thien-2-yl)-c-C-yclopentenepyridine) (acac)] (Pt-2), where-acac is acetylacetonate, were synthesized and characterized. Apart from,conventional phosphorescence of single molecules (ME-monomer emission), complexes Pt-1 and Pt-2 also exhibit excimer emission (BB) when embedded into phospholipid vesicles, that is assigned to emissive Pt-Pt excimers. The BE intensity. in-vesicular media appeared to depend on the viscosity of the vesicles and the concentration of the embedded,complex. Differences in the EE properties of complexes Pt-1 and Pt-2 are Correlated with the energies of the pi-character frontier orbitals defined by the design of the cyclometalating phenylpyridine ligand. Higher energies of the frontier pi-orbitals (HOMO and LUMO) naturally promote stronger pi=pi interactions, thus obstructing the Pt-II-Pt-II interaction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据