期刊
INORGANIC CHEMISTRY
卷 56, 期 23, 页码 14383-14387出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b02630
关键词
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资金
- Universitat de Girona
- Spanish MINECO [CTQ014-59832-JIN]
- EU [UNGI08-4E-003]
The hydrogenation of nitrous oxide by PNP pincer ruthenium complexes supposes a promising way to functionalize a hazardous gas and reduce the greenhouse effect, generating dinitrogen and water. Here, by DFT calculations we describe not only the whole mechanism for such a green transformation but we unravel the fundamental role of water, without which the reaction could not go forward. Water assists mandatorily in the H transfer to generate the hydroxyl group together with the release of dinitrogen.
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