期刊
INORGANIC CHEMISTRY
卷 56, 期 13, 页码 7316-7319出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b00862
关键词
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资金
- Science and Engineering Research Board, Government of India [SB/S1/IC-14/2013]
- National University of Science and Technology, MISIS, Russia [K3-2016-029]
Postsynthetic modification is a promising tool for introducing multifunctional properties in metal organic frameworks (MOFs). The effects of postsynthetic metal addition/exchange in a barium-based MOF have been well examined toward their magnetic and electrical properties: The rattling motion of the extra framework organic cation is, responsible for the ferroelectric behavior. The strong magnetic frustration in Tb@l is found to arise from the nearly triangular arrangement of :Tb3+ ions in its secondary building unit along the chain direction.
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