期刊
MAGNETOCHEMISTRY
卷 6, 期 1, 页码 -出版社
MDPI
DOI: 10.3390/magnetochemistry6010001
关键词
asymmetric reaction; chiral imprinting; electrodeposition; chiral nickel
资金
- University of Modena and Reggio Emilia (Department of Engineering 'Enzo Ferrari')
- Weizmann Institute of Science (WIS)
Magnetoelectrochemistry is a branch of electrochemistry where magnetic fields play a vital role in the oxidation and reduction process of the molecules. When it comes to spin-dependent electrochemistry (SDE), becomes a new paradigm. This work presents electrochemical response during the chiral imprinting on working electrodes and the effects of potentiostatic and galvanostatic methods. We explore the use of the SDE concept, which is implemented for chiral-ferromagnetic (CFM) hybrid working electrodes, and we compare various electrochemical parameters affecting the quality of deposition. We electrochemically co-deposited nickel (Ni) with a chiral compound (tartaric acid) in its enantiopure forms (L and D), which allows us to obtain a chiral co-deposited nickel-tartaric acid (Ni-LTA or Ni-DTA) working electrode.
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