期刊
POLYMER CHEMISTRY
卷 11, 期 35, 页码 5559-5571出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0py00939c
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资金
- National Research Foundation (NRF), Singapore, under its National Research Foundation Investigatorship [NRF-NRFI05-2019-0001]
- Ministry of Education, Singapore, under its Academic Research Fund (AcRF) Tier 2 [MOE2017-T2-1-018]
Halogen bonding (XB) has been used to catalyze organic reactions and polymerizations, which is an emerging research area. Reversible complexation mediated polymerization (RCMP) is an XB-catalyzed living radical polymerization and is one of the most promising examples of the XB catalysis. RCMP utilizes alkyl iodides as initiating dormant species and electro-donating molecules and ions such as amines, iodide anions, and oxyanions as catalysts. Various initiating dormant species and catalysts were developed, enabiling the synthesis of well-defined homopolymers and block copolymers with complex architectures, chain-end functionalization, photo-polymerization, and industrial application. The use of inexpensive non-metallic catalysts and the accessibility to a wide range of polymer structures are attractive features of RCMP. This mini-review summarizes the current research status of RCMP and its uniqueness broughtviathe XB catalysis.
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