期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 74, 页码 10867-10870出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03808c
关键词
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资金
- MEXT, Japan [18K19050, 18H05208, 19K15518, 20H00381]
- E-IMR project
- Shorai Foundation for Science and Technology
- Mazda Foundation
- China Scholarship Council (CSC)
- Institute for Materials Research, Tohoku University
- Grants-in-Aid for Scientific Research [20H00381, 19K15518, 18H05208, 18K19050] Funding Source: KAKEN
The precise control of intra-lattice multiple electron transfers was demonstrated in the solvated and desolvated species of the tetraoxolene-bridged Fe honeycomb layer system, (NPr4)(2)[Fe-2(Cl(2)An)(3)]center dot(solv) (Cl(2)An(n-)= 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate; NPr4+= tetrapropylammonium cation), by the site-doping of the Cl(2)An(n-)bridging unit using X(2)An(n-)units with X = Br or F.
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