期刊
CHEMICAL SCIENCE
卷 11, 期 35, 页码 9691-9696出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sc04450d
关键词
-
资金
- JSPS KAKENHI [JP19K05451, JP18H02104, JP18H04386, 19J14128]
- Naito Foundation
- Japan Agency for Medical Research and Development (AMED) [JP20am0101098, JP20gm0910007]
- Cooperative Research Project of Research Center for Biomedical Engineering
- Grants-in-Aid for Scientific Research [19J14128] Funding Source: KAKEN
An aryne reaction with alkynyl sulfides affording benzo[b]thiophenes is disclosed. A wide range of 3-substituted benzothiophenes were synthesized from easily availableo-silylaryl triflates and alkynyl sulfides in a one-step intermolecular manner. The synthesis of diverse multisubstituted benzothiophene derivatives involving a pentacyclic compound was achieved by virtue of the good functional group tolerance and versatile C2 functionalizations.
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