4.6 Article

Fabricating a g-C3N4/CuO heterostructure with improved catalytic activity on the multicomponent synthesis of pyrimidoindazoles

期刊

JOURNAL OF NANOSTRUCTURE IN CHEMISTRY
卷 10, 期 4, 页码 289-308

出版社

SPRINGER HEIDELBERG
DOI: 10.1007/s40097-020-00350-0

关键词

g-C3N4/CuO; Pyrimidoindazole; Multicomponent reaction; BBD model; Microwave methods; Luminescence; Fluorophores

资金

  1. CSIR-SRF [09/844(0052)/2018 EMR-I]
  2. DST [SB/FT/CS-113/2013]

向作者/读者索取更多资源

A series of fluorescence-containing indazole-fused ring systems were made with the support ofg-C3N4/CuO as a catalyst via non-conventional (microwave) method. We have synthesizedg-C3N4/CuO nanocomposites by mechanochemical process; further, its morphology and composition were studied using various instrumental techniques like Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), and transmission electron microscopy (TEM). Also, we have synthesized pyrimido[1, 2-b] indazole-4-yl methanol motifs without any solvent in single-step methodology utilizing microwave irradiation. The pyrimido[1, 2-b] indazole-4-yl methanol motifs were optimized using response surface methodology (RSM). This preparation was effortlessly accessible, and the overview of the substrates was authorized. The pyrimidoindazole core structures exhibit the most remarkable photo physical properties. Most of the pyrimidoindazole scaffold appears in solvatochromism and excited with blue-green fluorescence shift while using ethyl acetate as solvent. This result indicates that synthesized pyrimidoindazole core motifs have prodigious potential as fluorophores which will help us to study several applications. Graphic abstract

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