期刊
GREEN CHEMISTRY
卷 22, 期 18, 页码 6170-6175出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0gc02168g
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资金
- CSIR, New Delhi
- DST, Govt. India [EMR/2016/000010]
- CSIR-CSMCRI [MLP-0027]
Phosphonation of quinoxalines and quinoxalin-2(1H)-ones utilizing aerobic oxygen as green oxidant under visible light conditions at room temperature has been described. Both quinoxalines and quinoxalin-2(1H)-ones are compatible with alkyl or aryl phosphonates and provided good yields of products through regioselective C-P bond formation under base/ligand-free conditions. Competitive experiments showed quinoxalin-2(1H)-ones are more reactive than quinoxalines under the present conditions, and the control experiments revealed the present transformation proceeds through a radical mechanism.
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