期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 56, 期 26, 页码 7462-7467出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.7b01482
关键词
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资金
- National Key Research and Development Program of China [2016YFB0301704]
- National Natural Science Foundation of China [21506021]
- Fundamental Research Funds for the Central Universities [DUT16RC(4)11]
A nanosized titanium silicalite-1 (TS-1) was synthesized in a tetrapropylammonium hydroxide hydrothermal system and was then extruded with silica and different additives (carborundum and SBA-1.5). The obtained TS-1 extrudates were characterized and evaluated in the epoxidation of 1-butene in a fixed-bed reactor. The catalytic performances are enhanced when carborundum and SBA-15 are introduced to the shaped catalysts, especially when using carborundum. The reasons for the deactivation of TS-1 and improvement of catalytic performance were studied. The mesopores in SBA-15 improve the diffusion property of substrates, leading to a higher catalytic activity. The high heat conductivity property of carborundum removes the exothermal rapidly, eliminating the side reactions and resulting in a higher stability.
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