期刊
CHEMICAL SOCIETY REVIEWS
卷 49, 期 18, 页码 6733-6754出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cs00815j
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资金
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany's Excellence Strategy [EXC 2008/1-390540038]
- China Scholarship Council
Small molecules such as H-2, N-2, CO, NH3, O(2)are ubiquitous stable species and their activation and role in the formation of value-added products are of fundamental importance in nature and industry. The last few decades have witnessed significant advances in the chemistry of heavy low-coordinate main-group elements, with a plethora of newly synthesised functional compounds, behaving like transition-metal complexes with respect to facile activation of such small molecules. Among them, silylenes have received particular attention in this vivid area of research showing even metal-free bond activation and catalysis. Recent striking discoveries in the chemistry of silylenes take advantage of narrow HOMO-LUMO energy gap and Lewis acid-base bifunctionality of divalent Si centres. The review is devoted to recent advances of using isolable silylenes and corresponding silylene-metal complexes for the activation of fundamental but inert molecules such as H-2, COx, N2O, O-2, H2O, NH3, C(2)H(4)and E-4(E = P, As).
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