期刊
MICROCHEMICAL JOURNAL
卷 158, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.microc.2020.105237
关键词
Electrochemical sensor; Oxygen plasma; ZnO nanoflowers; Simultaneous detection
资金
- Tianjin Natural Science Foundation [18JCZDJC99800, 17JCQNJC00900]
- National Natural Science Foundation of China [51502203]
- Tianjin Young Overseas High-level Talent Plans [01001502]
- Tianjin Science and Technology Foundation [17ZXZNGX00090]
- Tianjin Distinguished Professor Foundation of Young Researcher, Tianjin Development Program for Innovation and Entrepreneurship
In this paper, an oxygen plasma-treated ZnO nanoflower-based screen-printed electrode (SPE) is proposed as an electrochemical sensor for the simultaneous detection of dopamine (DA), and diclofenac sodium (DS). Scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy were applied to characterize the morphology and structure of the nanomaterials. The ZnO nanoflowers with a large specific surface area exhibited good electrochemical performance, and they were conducive to ion exchange. The electrochemical behaviors of DA, and DS were evaluated by cyclic voltammetry in the potential range of 0.3-1 V; the linear response ranges were 0.1-300, and 0.01-40 mu M, and the sensitivities were 0.26, and 0.37 mu A.mu M-1 cm(-2), respectively, with detection limits of 0.28, and 0.11 mu M. The selective detection of DA, and DS was evaluated in the presence of other compounds. The results revealed that the oxygen plasma-treated ZnO/SPE, as an electrochemical sensor, could simultaneously detect these substances with good stability and low detection limit. The proposed method was successfully applied using urine samples, and has a good recovery rate. In the future, it may serve as a new detection technology for drug detection and health monitoring.
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