期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 77, 页码 11469-11472出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc05056c
关键词
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资金
- National Natural Science Foundation of China [21801181]
- State Key Laboratory of Elemento-Organic Chemistry (Nankai University)
A practical copper-catalyzed highly regioselective 1,2-hydrocarboxylation of terminal 1,3-diene with carbon dioxide has been developed. Under mild reaction conditions, this chemistry afforded 2-benzyl-beta,gamma-unsaturated acid derivatives as products, which are a kind of important unit for bio-active molecules and versatile precursors for organic synthesis, with good functional group tolerance. The key intermediate in this transformation is illustrated by control experiments.
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