期刊
ORGANIC CHEMISTRY FRONTIERS
卷 7, 期 19, 页码 2950-2954出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00775g
关键词
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资金
- National Natural Science Foundation [21772046, 2193103]
- Subsidized Project for Cultivating Postgraduates' Innovative Ability in Scientific Research of Huaqiao University
An efficient Pd-catalyzed cyanation of aryl halides within situgenerated CN(-)anions is described. The CN(-)source stems from the quadruple cleavage of chlorodifluoromethane (ClCF2H) with sodium amide (NaNH2). This transformation features no requirement of a toxic CN source and avoids the problem of HCN generation associated with traditional methods. A series of aryl nitriles are obtained from aryl halides in good yields under mild reaction conditions.
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