期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 79, 页码 11775-11778出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc05340f
关键词
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资金
- National Natural Science Foundation of China [21472060, 21772058, 21072071]
- 111 Project [B17019]
- self-determined research funds of CCNU from the colleges' basic research and operation of MOE [CCNU17CG0011, CCNU17KYZHSY07, CCNU18KYZHSY06]
- China Postdoctoral Science Foundation [2018M632898]
- Shenzhen Science and Technology Innovation Commission [JCYJ20170412140251576]
An efficient C-P coupling reaction of enantiopure tert-butylmethylphosphine-boranes with aryl and heteroaryl halides is developed by using Pd(OAc)(2)/dppf as a catalyst, affording a series of (S) or (R)-Pchiral phosphines in moderate to high yields and with ee values up to 99% ee. Moreover, the reaction time could be reduced from 72 h to 6 h with increased ee values under microwave irradiation.
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