期刊
POLYMER CHEMISTRY
卷 11, 期 38, 页码 6157-6162出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0py01008a
关键词
-
资金
- National Science Foundation of China [21871273]
A novel thermoresponsive dynamic covalent chemistry was developed based on 1,6-conjugate addition between a stablepara-quinone methide, namely 2,6-di-t-butyl-7-phenyl-p-quinone methide (pQM), and thiol nucleophiles. When applying it in the formation of polymer networks, covalently cross-linked polymer bulk materials were developed with thermoresponsive dynamic properties. This new type of dynamic covalent polymer network possesses wonderful structure stability at room temperature but demonstrates excellent self-healable and recyclable properties at high temperatures above 100 degrees C. The new thermoresponsivepQM-thiol dynamic covalent chemistry expanded the scope of dynamic covalent polymer network materials.
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