期刊
ELECTROCHIMICA ACTA
卷 359, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2020.136928
关键词
Cobalt electrodeposition; Deep eutectic solvent; First growth stages; Substrate influence
资金
- (Fond Europe de Desarrollo Regional, FEDER) from the Spanish Ministerio de Economia y Competitiyidarl (MINECO) [TEC2017-85059-C3-2-R]
- Generalitat de Catalunya [2017-SGR-1442]
- CONACyT
The purpose of this systematic study was to investigate the effects of specific substrates and potential conditions applied while tailoring the morphology and chemical composition of nanostructured Co films. In particular, Co electrodeposition in sustainable choline chloride-urea deep eutectic solvent was assessed, using glassy carbon and two metals widely employed in electrocatalysis and biocompatible purposes, Pt and Au, as substrates for modification with Co. Various in situ electrochemical techniques were combined with a broad range of ex-situ characterization and chemical-composition techniques for a detailed analysis of the prepared Co films. Among the results, nanostructured Co films with high extended active surface areas and variable composition of oxo and hydroxyl species could be tuned by simply modulating the applied potential limits, and without using additives or surfactant agents. The study highlights the effectiveness of using deep eutectic solvent as suitable electrolyte for surface modification by controlled deposition of nanostructured Co films with further application in electrocatalysis. (c) 2020 Elsevier Ltd. All rights reserved.
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