期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 18, 期 37, 页码 7425-7430出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ob01431a
关键词
-
资金
- National Natural Science Foundation of China [21102132, 21172200]
An efficient approach to synthesize heteroaromatic 2-amines from one-pot desulfurization/dehydrogenative cyclization of aryl isothiocyanates withortho-substituted amines in water was developed. This approach tolerated a wide range of functional groups on the aromatic ring, providing a practical and environment-friendly process to synthesize heteroaromatic 2-amines in moderate to excellent yields. A plausible mechanism was proposed and the role of TBAB and Cu2O in the present strategy was suggested with the help of ESI mass spectrometry.
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