期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 81, 页码 12186-12189出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc05632d
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资金
- National Natural Science Foundation of China [21971075, 21734004, 21674038]
- Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates [2019B030301003]
Selective ring-opening polymerization of ethylene/propylene oxide from hydroxyl-functionalized carboxylic esters is achieved by use of metal-free Lewis pair catalysts. Subsequently, quantitativein situhydrolysis is conducted to afford well-defined alpha-carboxyl-omega-hydroxyl polyethers which are highly valuable for bioconjugation but usually synthesized by much more tedious and costly routes.
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