Two-dimensional co-crystallization of two carboxylic acid derivatives having dissimilar symmetries at the liquid/solid interface

By the co-assembly of two carboxylic acids with distinct symmetries and different numbers of carboxyl groups, we obtained two novel cocrystal structures at then-octanoic acid/HOPG interface, one of which was sustained by unoptimized R(2)2(8) hydrogen bonding. Benefiting from the bias-sensitivity of the BTB (1,3,5-tris(4-carboxyphenyl)benzene) molecule, a structure transition between the cocrystal network and a denser BTB lamella is achieved.