期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2020, 期 40, 页码 6368-6369出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202001088
关键词
Amination; Amines; EPR spectroscopy; Pyrrolidines; Radicals
The initial steps of the catalytic Hofmann-Loffler reaction include the formation of theN-halogenated amine with further formation of a nitrogen-centered radical. We had reported the presence and detection of a radical through EPR spectroscopy. Based on new data, we discuss the observed EPR signal.
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