期刊
GREEN SYNTHESIS AND CATALYSIS
卷 1, 期 2, 页码 83-85出版社
KEAI PUBLISHING LTD
DOI: 10.1016/j.gresc.2020.09.002
关键词
Axially chiral biaryls; Asymmetric Catellani reaction; C -H functionalization; Cross coupling; Divergent synthesis
资金
- National Instittue of General Medical Sciences [5R01GM125920-04]
This highlight summarizes a recent development of a catalytic enantioselective Catellani-type reaction for the synthesis of axially chiral biaryls. The chirality induction is solely governed by chiral norbornene ligand in the Pd mediated ortho C-H functionalization and ipso cross-coupling transformation. The preparative power of the methodology is demonstrated as a powerful manifold for the divergent synthesis of structurally diverse axially chiral biaryls and chiral fluorenols.
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