期刊
SCRIPTA MATERIALIA
卷 188, 期 -, 页码 302-306出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2020.07.046
关键词
Table-like magnetocaloric effect; HoNi2 alloys; Curie temperature; Hydrogen liquefaction
类别
资金
- JST-Mirai Program, Japan [JPMJMI18A3]
We show the giant magnetocaloric effect of HoNi2 compound can be tuned around hydrogen liquefaction temperature by substituting Ho with Gd and Ni with Co in Ho1-xGdxNi2-yCoy. While the Curie temperature of Ho1-xGdxNi2-yCoy can be tuned from 15 to 32 K originating from the lattice expansion of the cubic structure, giant entropy change of 22.0 J/kgK is retained near the hydrogen liquefaction temperature. A table-like entropy change observed in a broad temperature range of 20 to 32 K makes them promising as magnetocaloric materials for cryogenic magnetic refrigeration utilizing an Ericsson cycle. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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