期刊
ELECTROCHIMICA ACTA
卷 361, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2020.137041
关键词
Unburned charcoal; Hard carbon; Sodium-ion batteries; Lithium-ion batteries; Anode; High capacity
资金
- National Natural Scicncc Foundation of China [91953118]
- 111 Project [B13013]
Over the past years, the biomass-derived materials are receiving more and more attention as high-performance and low-cost anodes for sodium-ion batteries (SIBs) and lithium-ion batteries (LIBs). Herein, the hard carbon derived from unburned charcoal (UC-x) is prepared by acid and heat treatment. And it is inferred from morphological characterization that the unique net structure is favorable for electrolyte permeation and charge transfer for Na+/Li+ As a result, the UC-x electrode as an anode shows high specific capacity (150 m Ah g(-1) for SIBs and 350 m A h g(-1) for LIBs at 0.1 A g(-1)) and enhanced cycling stability (250 mA h g(-1) after 300 cycles for LIBs and 273 mA h g(-1) after 200 cycles for SIBs). In addition, UC-1200 possesses fast electrochemical kinetics for Na+/Li+ (1-6 x 10(-10) cm(2) s(-1) for Na+ and 1-2.5 x 10(-10) cm(2) s(-1) for Li+) and the dominated electrode reaction is mainly controlled by pseudocapacitance. In a word, this work provides a kind of unique biomass material as anodes for SIBs/LIBs from the reutilization of the waste and promotes the development of carbonaceous electrode materials. (C) 2020 Elsevier Ltd. All rights reserved.
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