期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 398, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jhazmat.2020.122977
关键词
Hydrothermal carbonization; Waste reclamation; Cation; Anion; Amendment
Cationic and anionic heavy metal contamination sometimes co-exists in soil systems, such as mining areas and shooting ranges, seriously threatens human health and ecological stability. In this study, iron-modified rice husk hydrochar showed commendable ability to immobilize both heavy metal cation (Pb) and anion (Sb) simultaneously in soils. Iron-modified rice husk hydrochar (HC12.5-180) (5%) amendment reduced the bioavailability (EX- and CB-fraction) of Pb and Sb by 25 and 40%, respectively, which were 8 and 5 times higher than that of pristine rice husk hydrochar (HC0-180) (5%) amendment. The cation (Pb) immobilization mainly depends on cation exchange with mineral components (K+, Ca2+, Na+, Mg2+), precipitation with nonmetallic anions (Cland SO42-), and complexation. Meanwhile, the iron oxides (FeO, Fe2O3, Fe3O4), formed during hydrothermal process, can be easily combined with anion (Sb) to form geochemically stable minerals. In conclusion, this work offered a practical and cost-effective technology based on the iron modification rice husk hydrochar for the immobilization of both anionic and cationic heavy metal contaminants in soils.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据