期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 83, 页码 12530-12533出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc05580h
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资金
- National Natural Science Foundation of China [21801163, 21702213]
- STU Scientific Research Foundation for Talents [NTF18003]
- Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme 2019 [GDUPS2019]
A photoredox/cobaloxime co-catalyzed coupling reaction of a-ketoacids and methacrylates to obtain allylic ketones is described. Without the cobaloxime catalyst, 1,4-dicarbonyl compounds are generated. The cobaloxime catalyst enables dehydrogenation to generate the formation of new olefins. The generality, good substrate scope and mild conditions are good features in the photoredox/cobaloxime catalysis protocol, and this method will provide new opportunities for the functionalization of more olefins.
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