期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 85, 页码 12957-12960出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc04986g
关键词
-
资金
- National Natural Science Foundation of China [21772075, 21532001, 21272101]
Herein, a highly regioselective propargylic benzylation with propargylic carbonates and benzyl 1,4-dihydropyridine derivatives was developed via a photoredox/palladium dual-catalyzed process, which represents a novel catalytic model for non-terminal propargylic functionalization. The reaction showed excellent regioselectivity and functional group compatibility. A radical coupling mechanism between the propargylic radical and benzyl radical was proposed.
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