期刊
MATERIALS TODAY-PROCEEDINGS
卷 31, 期 -, 页码 S122-S129出版社
ELSEVIER
DOI: 10.1016/j.matpr.2020.06.398
关键词
NH-Carbenes; Metal; Synthesis; Applications; Catalysis; Biological
N-heterocyclic carbenes are of central importance in many domains of chemistry such as organometallic, catalysis and bioinorganic. Their great importance is due to their ability to act as ligands with a large number of transition metals. These Metal-NHCs are used as catalysts in various organic transformations with good biological properties. A wide range of Metals - NHC has been found to be useful as a catalyst in various reactions using Ru, Pd, Ir, Au and Ag. This review examines the different classes of Metal - NHCs and their applications as effective catalysts in several types of organic processes, for example the formation of amide linkage, hydrogenation, isomerization, cycloisomerization, cyclopropanation, hydrosilylation, allylation and desallylation, enol-ester synthesis, heterocycle synthesis, C - C alkyne coupling. (C) 2020 The Authors. Published by Elsevier Ltd.
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