4.7 Article

Liquid-core polymer optical fi bers for luminescent waveguide applications

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MATERIALS & DESIGN
卷 196, 期 -, 页码 -

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ELSEVIER SCI LTD
DOI: 10.1016/j.matdes.2020.109131

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Optical fibers; Molecular orientation; Light conversion; Strain sensor; Semi-crystalline polymer

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Luminescent polymer optical fibers provide a flexible platform for sensor applications. Photoluminescent liquid -core polymer optical fibers (LiCo-POFs), produced by a co-extrusion of a low refractive index semi-crystalline fluoropolymer sheath with a glycerol core, are presented. Substituting a POF's solid polymer core with a transparent liquid yields luminescent waveguides with extra mechanical flexibility, enabling unique applications like strain sensing. Light conversion and guidance in LiCo-POFs were both achieved simultaneously by doping of the glycerol core with a fluorescent dye. X-ray analysis showed a strong impact of drawing on fiber sheath morphology, and in consequence on both mechanical and optical properties: as the molecular orientation of the sheath increases, tensile strength improves and light attenuation decreases. Excessive drawing leads to micro -voids in the sheath material, causing light scattering, which negatively affects both attenuation and light -conversion. It has been found that both the sheath structure and the sheath and core cross-sectional areas are important design parameters regarding the mechanical and optical performance of LiCo-POFs. A novel principle of an optical strain sensor based on self-absorption peak-shifts is demonstrated; it allows detection of sub -millimeter displacements, both in a reversible elastic as well as in an irreversible inelastic sensor range. (c) 2020 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

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