期刊
CRYSTENGCOMM
卷 17, 期 22, 页码 4070-4074出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ce00618j
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资金
- IWT (Vlaanderen)
- KU Leuven
- FWO [G.0486.12, G.0256.14]
- Belspo [IAP 7/05]
The synthesis of Zr-MOFs under green, industrially feasible conditions was investigated. Two new compounds with bcu-topology and the fluorinated analogue of UiO-66 exhibiting fcu-topology were obtained and characterised. All products exhibit permanent porosity. In the bcu-frameworks the interaction with sulfate anions apparently induces an unusual eightfold connectivity of the Zr cluster.
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