期刊
NANO ENERGY
卷 77, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.nanoen.2020.105161
关键词
Organic solar cells; Noncovalent conformation locks; Polymer donors; Planarity; Hole mobility
类别
资金
- National Key Research and Development Program of China [2017YFA0206600]
- National Natural Science Foundation of China [51773045, 21772030, 51922032, 21961160720]
- Youth Association for Promoting Innovation (CAS)
The mechanism that how noncovalent conformation locks (NCLs) to improve the photovoltaic performance of polymer donors was investigated. By developing a model system with three structure-related copolymers W1, W2 and W-3, a clear correlation was found between the locking strength in polymer backbone and the photovoltaic performance. W1 with the strongest S center dot center dot center dot O and F center dot center dot center dot H double-side locking gave the highest power conversion efficiency (PCE) of 16.23%, while W2 with a S center dot center dot center dot O single-side locking and W3 with a weakened S center dot center dot center dot O locking caused by Cl-H steric repulsion gave lower PCEs of 11.73% and 0.92%, respectively. With the aid of single crystal X-ray diffraction analysis, density functional theory calculation, grazing-incidence wide-angle X-ray scattering analysis, atomic force microscope study and device characterization, the functions of NCLs in improving the planarity, packing, crystallinity and hole mobility of polymers, as well as the morphology of blend films, were illuminated in detail.
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