期刊
CHEMICAL COMMUNICATIONS
卷 56, 期 92, 页码 14369-14372出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc05942k
关键词
-
An iron complex bearing the facially capping tridentate 1,4,7-triazacyclononane ligand mimics structural and functional features of alpha-ketoglutarate (alpha-KG) dependent enzymes, and engages in enzyme-like catalytic O-2 activation coupled to alpha-ketoacid decarboxylation, oxygenating sulfides. This system constitutes a rare case of non-enzymatic catalytic O-2 activation, cycling between Fe-II and Fe-IV(O).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据