期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 18, 期 43, 页码 8771-8792出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ob01741h
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- NISER
- CSIR [02(0338)/18/EMR-II]
In organic synthesis, transition-metal and photoredox-catalysis-based reaction systems are emerging trends for the construction of C-S bonds. Many review articles have recently appeared in this field; however, we present herein an overview of metal-free C-S coupling reactions using thiols or disulfides as sulfur surrogates. The oxidants we have considered include peroxides, tert-butyl nitrite (TBN), DDQ, iodine reagents, and molecular oxygen. In addition, selective electrochemical oxidative transformations are also covered with mechanistic details.
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