期刊
CRYSTENGCOMM
卷 17, 期 47, 页码 9055-9061出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ce01648g
关键词
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资金
- NSF of China [21201109, 21373122, 21301106]
- Project of Hubei PEO [Q20131304, Q20141201]
- NSF of Hubei [2014CFB277]
- Graduate Student Research Innovation Fund of CTGU [CX2014094]
- Training Excellent Master's Thesis Fund of CTGU [PY2015074]
Two unique entangled Cd(II) coordination polymers, {[Cd-2(m-pdoa)(2)(dpa)(3)(H2O)]}(n) (1) and {[Cd(m-pdoa)(bpp) (H2O)]center dot 2H(2)O} n (2) (m-H(2)pdoa = 1,3-phenylenedioxy diacetic acid, dpa = 4,4'-dipyridylamine; bpp = 1,3-di.4-pyridyl)propane), have been modulated using flexible/semi-rigid mixed aromatic carboxylate and pyridine derivative ligands and characterized using elemental analysis, infrared spectra (IR), powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. 1 shows the first topological motifs of mutual-embedded bilayers originating from two reverse 2D 4(4)-sql layers with 1D single side arms in an alternating fashion, and thus affording a 3D polythreaded structure featuring poly-pseudo-rotaxane that exhibits a new 3D (3,3,3,3,3,5,5,5)-connected self-penetrated H-bonding net. Whereas 2 displays rare 2D -> 2D homochiral interpenetrated layers propagating from 4(4)-sql chiral layers. Additionally, thermal stabilities and luminescent properties for 1 and 2 were also discussed.
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