4.7 Article

Design of mass-controllable NiCo2S4/Ketjen Black nanocomposite electrodes for high performance supercapacitors

期刊

CRYSTENGCOMM
卷 17, 期 39, 页码 7583-7591

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ce01324k

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资金

  1. National Natural Science Foundation of China [21353003]
  2. Special Innovation Talents of Harbin Science and Technology [2013RFQXJ145]
  3. Fundamental Research Funds of the Central University (HEUCFZ)
  4. Key Program of the Natural Science Foundation of Heilongjiang Province [ZD201219]
  5. Program of International S&T Cooperation special project [2013DFA50480]

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NiCo2S4/Ketjen Black nanocomposites have been successfully fabricated on nickel foam by a facile two-step solution-based method. Compared with the pure NiCo2S4 electrode (Ni1K0), the NiCo2S4/KB nanocomposite electrodes (Ni1K0.5, Ni1K0.25, and Ni1K0.125) with controllable mass loadings show significantly enhanced electrochemical performance. Electrochemical measurements demonstrate that the Ni1K0.25 electrode has a competitive areal specific capacitance (10.10 F cm(-2) at 10 mA cm(-2)), good rate capacitance (38.41% capacitance retention at 40 mA cm(-2)) and excellent cycling stability (92.1% capacitance retention, 6000 cycles at 10 mA cm(-2)). Such high performance may promote NiCo2S4/KB nanocomposites in practical application for supercapacitors.

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