4.7 Article

A one-dimensional switchable dielectric material with Pd uptake function: [(CH2)3NH2S]2BiCl5

期刊

CHEMICAL COMMUNICATIONS
卷 56, 期 89, 页码 13764-13767

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc05648k

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资金

  1. National Natural Science Foundation of China [21771037, 21805033]
  2. Natural Science Foundation of Jiangsu Province (JSNSF) [BK20170659]

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A semiconductor material [(CH2)(3)NH2S](2)BiCl5 (1) exhibits dielectric switching and Pd uptake functions. The thioether group in 1 provides an opportunity for Pd uptake. After 1 adsorbs Pd, the dielectric switching disappears, so that Pd adsorption can be monitored by dielectric measurements. Moreover, the material becomes an insulator after adsorbing Pd.

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