期刊
NEW JOURNAL OF CHEMISTRY
卷 44, 期 46, 页码 20358-20366出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0nj04526h
关键词
-
资金
- National Natural Science Foundation of China [21671157, 21371143, 21501139]
Due to the increasingly severe environmental pollution, there is an urgent need to find a new catalyst with high efficiency and stability for deep desulfurization of fuels. In this work, hybrid material based on vanadium-substituted Dawson type polyoxometalate and poly ionic liquid was facilely prepared and successfully loaded on different carbon materials to produce a supported catalyst for oxidative desulfurization. The test result shows that the catalyst P[C2VP]MoV/AC possesses high activity with the DBT conversion of 99.2%. At the same time, the catalyst with large specific surface area has more opportunities to react with sulfides and thus possesses high activity. According to the kinetic study, it is confirmed that the oxidation reaction of DBT follows first-order kinetics.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据