期刊
DALTON TRANSACTIONS
卷 49, 期 47, 页码 17414-17420出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt03312j
关键词
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资金
- National Natural Science Foundation of China [21773122, 21471083]
- Science and Technology Foundation for Creative Research Group of Hubei Normal University [2019CZ08]
Three novel lanthanide-biradical complexes {[Ln(hfac)(3)](2)(mbisNITPyPh)(H2O)}{[Ln(hfac)(3)](mbisNITPyPh)}center dot CHCl3 (1-Gd; 2-Tb; 3-Dy) were successfully achieved by reacting the biradical mbisNITPyPh (5-(3-pyridyl)-1,3-bis(1-oxyl-3 '-oxido-4 ',4 ',5 ',5 '-tetramethyl-4,5-hydro-1H-imidazol-2-yl)benzene) with Ln(hfac)(3)center dot 2H(2)O (hfac = hexafluoroacetylacetonate). These Ln-biradical complexes consist of two kinds of spin moieties, namely, dinuclear {[Ln(hfac)(3)](2)(mbisNITPyPh)(H2O)} and mononuclear {[Ln(hfac)(3)](mbisNITPyPh)}, in which two adjacent dinuclear units are linked by intermolecular hydrogen bonds involving the uncoordinated nitroxide units and the coordinated water molecules of Ln ions, forming a cyclic tetranuclear structure unit. The magnetization study reveals that intramolecular Ln(III)-coordinated NO ferromagnetic interactions are dominant in the present system. Moreover, the clear frequency dependence of ac magnetic susceptibilities of complex 3-Dy is indicative of slow relaxation of magnetization behavior, indicating its single-molecule magnet nature.
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