期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 10, 期 22, 页码 7681-7696出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cy01167c
关键词
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资金
- Brazilian CNPq funding agency
- Brazilian CAPES funding agency
- Ministerio de Ciencia, Innovacion y Universidades [RTI2018-099668-BC22]
- Junta de Andalucia [UMA18-FEDERJA-126]
- FEDER funds [UMA18-FEDERJA-126]
TiO2 nanoparticles dispersed in ordered mesoporous CMK-3 carbon with different Ti contents were successfully synthesized and their activity in the photocatalytic degradation of ibuprofen was presented. The photocatalysts were characterized by X-ray diffraction (XRD), nitrogen adsorption-desorption isotherms, diffuse reflectance, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM-FEG) and transmission electron microscopy (TEM). A simple theoretical-computational study through single point energy calculations was also presented. Diffractograms, Raman, and XPS spectra confirmed the formation of anatase and graphitic carbon. Low-angle XRD, N-2 physisorption and the TEM images indicated that the CMK-3 support does not undergo a significant change in the mesoporous structure after the insertion of TiO2. The I-D/I-G ratio observed in the Raman spectra did not vary significantly with an increase in the titanium content, which shows that the crystallinity of CMK-3 is practically unchanged. Anatase crystallite sizes vary from 8 to 15 nm and specific areas vary from 348 to 586 m(2) g(-1), depending on the TiO2 content. The single point energy calculations confirmed the lowest energy to stabilize the titanium oxide and carbon composite for the sample with 1% of Ti compared to 8 and 18%. The 1% Ti2O/CMK-3 photocatalyst exhibited the best photocatalytic performance, reaching 100% degradation in just 5 min. Chemical oxygen demand and total organic carbon results confirmed the mineralization of ibuprofen. The degradation and mineralization mechanism of ibuprofen follows a sequence of radical reactions that occur in solution and on the solid surface, and may lead to the formation of intermediates before its mineralization.
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