期刊
ORGANIC LETTERS
卷 22, 期 22, 页码 9059-9064出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c03444
关键词
-
资金
- JSPS KAKENHI [JP 18K19078, JP 17H06092]
- Kyoto Technoscience Center
- Japanese government (MEXT) scholarship
A Pd-catalyzed regioselective C-H alkenylation of allylic alcohols with electron-deficient alkenes has been developed. The key to success is the introduction of bidentately coordinating phenanthroline directing group, which enables the otherwise challenging and regioselective C-H activation at the proximal alkenyl C-H bonds over the conceivably competitive allylic C-O bond activation. The same Pd/phenanthroline system is efficient for the C-H alkynylation of allylic alcohols with alkynyl bromides.
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