3.8 Article

n-Octyl-3-methylpipyridinium bromide ([OMePPy]+Br-): novel ionic liquid to promote green synthesis of polycyclic fused acridines

期刊

IRANIAN JOURNAL OF CATALYSIS
卷 10, 期 4, 页码 325-331

出版社

ISLAMIC AZAD UNIV, SHAHREZA BRANCH

关键词

Acridines; Ionic liquid; Isatin; Multi-component reaction (MCR); Green chemistry

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  1. Alzahra University

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In this research various polycyclic fused acridines were synthesized via the highly efficient and green one-step four-component reaction between isatins, dimedone, various amines, and dimethylacetylenedicarboxylates (DMAD/DEAD) in the presence of n-octyl-3-methylpipyridinium bromide ([OMePPy]Br-+(-)) as a newly prepared ionic liquid, in absolute green situations at room temperature under solvent-free conditions. The ionic liquid characterized by H-1 NMR, C-13 NMR, GC-MASS, TGA/ DTG, EDX, and FESEM techniques Utilizing an eco-friendly and simply synthesized ionic liquid, green and economic reaction media, and preparing a wide range of polycyclic fused acridines in good yields are some highlighted aspects of the reported protocol.

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