期刊
INORGANIC CHEMISTRY
卷 59, 期 23, 页码 16783-16788出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c02832
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资金
- DFG [BU 2725/8-1, HA 3466/8-3]
The synthesis of a second beryllium bromide modification, beta-BeBr2, was accomplished through recrystallization of alpha-BeBr2 from benzene in the presence of cyclo-decamethylpentasiloxane. This phase was analyzed via single-crystal X-ray diffraction and IR and Raman spectroscopy as well as density functional theory calculations. This enabled a comparison to alpha-BeBr2 and the alpha and beta phases of beryllium chloride and iodide.
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