期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 10, 期 23, 页码 8026-8033出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cy01636e
关键词
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资金
- National Key Research and Development Program of China [2018YFA0208600, 2018YFA0704502]
- National Science Foundation of China [22071245, 21671188, 21871263, 21520102001]
- Key Research Program of Frontier Science, Chinese Academy of Sciences [QYZDJ-SSW-SLH045]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Youth Innovation Promotion Association, Chinese Academy of Sciences [Y201850]
The design and preparation of porous catalysts with multiple catalytically active sites for synergistically catalytic conversion of CO2 still remains a challenge. Herein, cobalt porphyrin as a Lewis acidic active site was introduced in imidazolium-functionalized cationic covalent triazine frameworks (denoted as Co-PCCTFs) via copolymerization of cobalt 5,10,15,20-tetrakis(4-cyanophenyl)porphyrin (Co-TPPCN) and 1,3-bis(4-cyanophenyl) imidazolium chloride ([BCIM]Cl). The obtained bifunctional Co-PCCTFs with positively charged imidazolium groups have high BET surface areas and show sufficient CO2 adsorption uptakes. The nucleophilic halide anions of the imidazolium parts and the cobalt porphyrin Lewis acid sites were positioned in close proximity so that the Co-PCCTFs could synergistically activate substrates and intermediates. Compared with ICTF-400 free of Co2+ that was obtained from [BCIM]Cl, Co-PCCTF5 exhibited enhanced activity for the cycloaddition of CO2 to epoxides to produce cyclic carbonates without a cocatalyst under mild conditions. Moreover, Co-PCCTF5 is sufficiently stable so that it could be reused more than 5 times without loss of catalytic activity. This work provides a new approach for the design and preparation of efficient multifunctional catalysts with multiple sites for synergistic catalysis.
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